Thermodynamic Parameters for Transfer of Hydrocarbons from Water to Interior of Dodecyl Sulfate Micelles and from Water to Pure Liquid Hydrocarbon State
Hydrocarbon |
Water --> Micelle Interior |
Water --> Pure Liquid Hydrocarbon |
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ΔGo (kcal/mol) | ΔHo (kcal/mol) | ΔSo (cal/deg mol) | ΔGo (kcal/mol) | ΔHo (kcal/mol) | ΔSo (cal/deg mol) | |
Ethane | -3.45 | +2.0 | +18.3 | -3.9 | +2.5 | +21 |
Propane | -4.23 | +1.0 | +17.5 | -4.9 | +1.7 | +22 |
Butane | -5.13 | 0 | +17.2 | -5.9 | +0.8 | +23 |
from Tanford, The Hydrophobic Effect, 2nd. ed.