Thermodynamic Parameters for Transfer of Aliphatic Alcohols from the Pure Liquid to Water at 25oC. (enthalpy determined by calorimeter)
alcohol | μ w0-μ ROH0 (cal/mol) | H w0-H ROH0 (cal/mol) | S w0-S ROH0 (cal/deg mol) | (Cp)w0-(Cp)ROH0 (cal/degmol) |
ethanol | 760 | -2430 | -10.7 | 39 |
n-propanol | 1580 | -2420 | -13.4 | 56 |
n-butanol | 2400 | -2250 | -15.6 | 72 |
n-pentanol | 3222 | -1870 | -17.1 | 84 |
from Tanford, The Hydrophobic Effect, 2nd. ed.