Dr. Henry Jakubowski
LAST UPDATE: Saturday, December 13, 2008 08:23 AM
CLASS SCHEDULE AND ASSIGNMENTS
To do well in chemistry and get the most out of classroom experiences,, you should be prepared for each class. I will post reading and other assignments for the next class by 5PM of the class day we just completed. For example, after Class 1 ( 8/31 W), you should prepare for class 2 (9/2) by reading the assigned text and doing the JIT assignment BEFORE YOU COME TO CLASS 2.
Tutors will be available: TBA
Class | Date | Topics for class |
Pre-class Reading Assignment |
JIT Assignment - Complete before coming to class! | |
1 |
8/28 R A2 |
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Welcome, Distribute Lab Manual; - Intro - What Chemists Do: Synthesize, Purify, Analyze; - Atoms, Molecules, Mixtures, and Separations
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2 |
9/1 M A4 |
-review syllabus; -review mixtures, their complexities and their separations; chemical vs physical reactions - Understanding chemical and biological complexity: Macroscopic, Nanoscopic, Mathematical, and Symbolic -Problem Solving - Dimensional Analysis |
Chapt 1 |
1B. SIG FIGS Chapt 1: Matter and Measurements
Gp Worksheet: Dimension Analyses
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3 |
9/3 W A6 |
- Is Lake Sag filled with oil and sulfuric acid? - Laws of Matter; - Dalton's Atomic Theory;
- The Divisible
Atom: cathode rays/demo;
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Chapt 2 33-46. |
Paper Problems: Sulfuric Acid, Oil and Lake Sag
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4 |
9/5 F A2 |
Quiz.
- Millikan Oil Drop, calculation of e; - Rutherford, nuclear atom - read about this yourself and see web links; planetary model;
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Atomic Masses; isotopes and weighted - first ionization energy – shells; - Lewis Dot structure - intro to bonding
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Chapt 2 46-52 |
Paper Problems: Millikan Oil Drop Exp |
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5 |
9/9 T A4 |
- Lewis Dot structure - ionic, covalent, and polar covalent bonding
- FON and electronegativity; - Lewis Structures complete Lewis struct sheet in lab 2 |
Finish Chapt 2; Read: Ch 7: |
Paper Problem:
Isotopes of chlorine;
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6 |
9/11 |
Quiz: Lewis Structures - Lewis Structures; Salts, Acids, Acid reactivity and Lewis structures; - pushing electrons: Reaction Mechanisms; - acids and bases; - polyatomic or molecular ions; naming molecular ions
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Ch 7: |
Lewis Structure Worksheet
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7 |
9/15 M A2 |
Qz: Reaction Mechanism - Electron Push - Salts of molecular ions; Chapt 3 - Chemical Equations; balancing chem equations; - mole and molar mass - simple stoichiometry: gravimetric analyses - prep for Lab 3 (9/16)
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Chapt 3, pg 69-81; |
Paper Problem: Salts of Molecular Ions; - review answer key for dimensional analysis, page 2, on Moodle |
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8 |
9/17 W A4 |
- Examples typical types of stoich: - limiting/excess reagent, % composition, empirical formula, combustion analysis
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Chapt 3, pg 81-84; 93-97 |
-Paper Problem Set: Stoichiometry Problem Set 1 sent by email on 9/13 Sat AM |
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9 |
9/19 F A6 |
- Examples typical types of stoich: - limiting/excess reagent, % composition, empirical formula, combustion analysis
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Chapt 3 92-104 |
-Paper Problem Set: Stoichiometry Problem Set 2 sent by email on 9/13 Sat AM
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10 |
9/23 T B2 |
Solution stoichiometry in class and in lab on 9/25 |
All Chapter 3 |
- Paper Problem Set: Stoichiometry Problem Set 3 - Solution Stoichiometry and In lab on 9/25 |
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Benedictine Heritage Day | |||||
11 |
9/26 F B4 |
TEST 1 |
REVIEW |
Daily Learning Goals (no solution stoichiometry)
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12 |
9/30 T B6 |
-Review Test; - Lb 4: % Acetic Acid Solutions - are they the same? - What's in the Beaker; Electrolytes - Lab 2 Data - Precipitation Reactions; Molecular, Ionic, and Net Ionic Equations; Solubility Rules (See pg 112; also OLSG) |
Chapt 4 pg 107--116 |
none |
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FREE DAY 10/2-3 | |||||
13 |
10/6 M B2 |
- Precipitation Reactions; Molecular, Ionic, and Net Ionic Equations;
Solubility Rules (See pg 112; also OLSG) - Strong and Weak Acids and bases; conjugate acids/bases; -Mechanisms; Strengths; Resonances
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Chapt 4 107--116 |
What's in the Beaker (handed out in class)
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14 |
10/8 W B4 |
-Acid/Base. What is the stronger acid, HOCl or HClO4 (use Lewis structures and mechanisms) -Start Redox reactions |
Chapt 4 finish chapter omit Section 4.9 |
Acid Strength worksheet |
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15 |
10/10 F B6 |
- Redox reactions; - Strength oxid agent/reducing agent (EN, Core Charge) - oxidation #; - balance redox eq. - acid. (You will only need to know the 1/2 rx method for balancing Redox equations, and only in acidic solutions)
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Chapt 4 finish chapter omit Section 4.9 |
Challenge Problem: Ethanol, Acetic Acid and resonance
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16 |
10/14 T B2 |
Intro to Quantum Chemistry: the Dalton, the Plum Pudding (Thompson), The Planetary Atom (Rutherford) - review; Forces, acceleration, oscillating charges and fields;
The instability of the planetary atom |
Start Chapt 5 |
Name that Reaction: | Answer Key Go to the link, print it out, and hand it in in class. I will accept one per group (your present group at your table) with all your names on it. No individual assignments accepted.
Print out Hints and Common Mistakes for help. |
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17 |
10/16 R B4 |
Quiz: OLSG Web Links for 10/16 - properties of waves: reflection, refraction, diffraction, interference (constructive/destructive), superposition (adding); - light as a wave - Force, Energy, and work; |
Chapt 5, pg 147-156 |
Paper Problems: POGIL - Intro to Quantum 1: Force, Energy, and Work - Pages 1-3 only
On OLSG view all links for:
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18 |
10/20 M B6 |
- Problem with planetary model: discrete energies, radii, instability; fields - light as a particle: Photoelectric effect - light interactions with matter: absorption/emission spectra gases; - |
Chapt 5; pg 170-181 |
5A: Quantum I
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19 |
10/22 W C2 |
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Empirical Equation to predict line spectra: Rydberg Eq;
- electron as a wave: deBroglie, Bohr, Schrodinger, and Heisenberg - Wave Functions, quantum numbers, and orbitals - Electron Configurations; |
finish Chapt 5 |
Paper Homework: Energy Levels and the H atom |
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20 |
10/24 F C4 |
- review wavelike properties of atoms; - Orbitals; quantum numbers, and electron Configurations; |
Chapt 6, pg 185-194 |
Paper Homework: Electronic configurations
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21 |
10/28 T C6 |
- Quz: electron config and energy levels. - UV/Vis absorption/emission; ESR, NMR; review potential and kinetic energies of electrons - review Columbs law - Zeff; - Periodic Trends in atomic and ionic radii;
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Chapt 6, pg 185-194 |
5B: Quantum 2 |
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22 |
10/30 R C2 |
- periodic trends in ionization energy, electron affinity - ionic bonds; Lattice Energy, Born-Haber cycle;
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Chapt 6: 195-200 (skip 201-215) |
5/6: periodicity 1
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23 |
11/3 M C4 |
TEST 2 (2008: Review Tues Evening 7-9 |
REVIEW | ||
24 |
11/5 W C6 |
Covalent Bond; Lewis Structures 2 (2008: on 11/3) |
Chapt 7, pg 226-242(review) |
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25 |
11/7 F C2 |
Lewis Structures 2; Bond Energy, Quant Mechanical Explanation covalent bond; VSEPR; (2008: on 11/5)
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Chapt 7, pg 242-250 |
Lewis Structures 2 |
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26 |
11/11 T C4 |
- Trends in Bond Energies - VSEPR, Polarity, Dipoles; - Electronegativity,
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Chapt 7, 242-250; 224-225
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Electron Pair and Molecule Geometry,
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27 |
11/13 R C6 |
- Review VSEPR geometry - Qz: VSEPR - Valence Bond Theory - overlap of atomic orbitals - Hybridization
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Finish Chapt 7 |
In class activity - Hybridization |
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28 |
11/17 M D2 |
- Homework Qz: O hybridization in H2CO - hybridization and VSEPR: sp, sp2, sp3, sp3d, sp3d2 - Polarity and Dipole Moment
- Molecular Orbital Theory - Bond Order - Spartan Electron Densities:CH4 to HF, H2 to LiH, H3O+ and formal charges
- Bond Energies and Trends: H-H and H-F, N2 and H2 - Avg bond energies: H2, F2, I2, HF, and HI: electronegatiivty
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Chapt 7 |
7A: Lewis and vsepr
Turn in as a group homework quiz a drawing and electron box diagram showing the hybridization of oxygen in H2CO, formaldedye (we did this example on 11/13 in class for the C atom)
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29 |
11/19 W D4
11/20 R D5 in lab |
- Energy, Energy Conservation, Internal Energy, - State Functions. - PV Work, ΔE = q + w. Signs of q, W, E; - Enthalpy, ΔH; First Law |
Chapt 8 |
7b: hybridization and MOs Chapt 8: 273-285
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30 |
11/21 F D6 |
-Standard State -ΔH and Standard enthalpy formation - Hess's Law, |
Chapt 8 |
Chapt 8: 289-296
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31 |
11/25 T D2 |
- Heat Capacity
- Calculation ΔH rx's from: calorimetry: |
Chapt 8 (omit 298-304) |
8A: delta h Paper Homework: ΔH of Glucose and Hexane: To in your group and submit one per group.
Chapt 8: 285-289
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Thanksgiving 11/26-28 | |||||
32 |
12/2 T D4 |
Gas Laws: Boyle's, Charlie's, Avogadro's, Ideal |
Chapt 9
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8B: Heat capacity and calorimetry Chapt 9:315-330 |
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33 |
12/4 R D6 |
TEST 3 |
Review | ||
34 |
12/8 M D2 |
Ideal Gas Law/KMT problems |
Chapt 9 |
Paper Homework: Ideal Gas and KMT problems Redo of Part 1, Test 3 332-337; |
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35 |
12/10 W D4 |
Problem Solving - MCQ |
Review |
Topic 3 - Concept Inventory Multiple Choice Quest |
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36 |
12/12 F D6 |
Course Survey Problem Solving - MCQ |
Review |
Topic 3 - More Review Multiple Choice Questions More Multiple Choice Questions:
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Review Session: TBA Monday 12/15: ASC 104 ; 9:30 |
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Final Exam: Thursday, December 18: 1-3 PM. Room: ASC 121 Note: You will not be allowed to bring a graphing calculator into the final exam. A regular calculator that can do scientific notation will be adequate. |