Reactivity in Chemistry

Ligand Substitution in Coordination Complexes

LS1. Introduction to Ligand Substitution

LS2.  Mechanism of Ligand Substitution

LS3.   Kinetics of Associative Mechanism

LS4.  Kinetics of Dissociative Mechanism

LS5.  Activation Parameters

LS6Some Reasons for Differing Mechanisms

LS7.  The Trans Effect

LS8.  Solutions to Selected Problems

 

This site was written by Chris P. Schaller, Ph.D., College of Saint Benedict / Saint John's University (retired) with other authors as noted.  It is freely available for educational use.

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Structure & Reactivity in Organic, Biological and Inorganic Chemistry by Chris Schaller is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License

Send corrections to cschaller@csbsju.edu

This material is based upon work supported by the National Science Foundation under Grant No. 1043566.

Any opinions, findings, and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the National Science Foundation.

 

 

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