CHAPTER 3 - CARBOHYDRATES/GLYCANS
A: Mono- and Disaccharides
03/14/16
Learning Goals/Objectives for Chapter 3A: After class and
this reading, students will be able to
- define a sugar
- apply knowledge about reactions at carbonyl carbons of
aldehyde and ketones in the formation of hemiacetals/hemiketals
and acetals/ketals from organic chemistry to draw mechanics
showing cyclization of aldoses and ketoses and (hemiacetal/hemiketal
formation) and of polymerization of aldoses and ketones to form
dissacharide and polysaccharide (acetal/ketals).
- draw open chain, Haworth (planar), and puckered (nonplanar)
representations of 6 member cyclic sugars
- know the names of common trioses, ribose (5C) and hexoses
and draw open chain, Haworth, and puckered representations of
each
- differentiate between enantiomers, diastereomers and anomers
of the hexoses
- explain the difference between reducing and nonreducing
dissacharides
- draw the structure and name common sugar derivatives of the
hexoses
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The link below is an extraordinary and free resource on glycobiology.
It defines the word "glycan" as a "generic term for any
sugar or assembly of sugars, in free form or attached to another
molecule" and "is used interchangeably ... with
saccharide or
carbohydrate."
A1.
Monosaccharides Structures
A2.
Isomers
A3.
Monosaccharide Derivatives
A4.
Formation of Hemiacetals, Acetals, and Disaccharides
A5.
Recent Links and References
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Monosaccharides
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